Two New Copper(II) Complexes of 1-Butyl-1H-1,2,4-triazole: Synthesis, Characterization and Electrocatalytic Activity
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چکیده
Dois novos complexos de cobre(II), [Cu 4 Cl 6 O(C 6 H 11 N 3 ) 4 ] e [CuBr 2 (C 6 H 11 N 3 ) 4 ], foram sintetizados e caracterizados por difratometria de raios X de monocristal, espectroscopia de absorção no infravermelho e análise elementar. Os compostos apresentaram voltamogramas cíclicos similares e boas atividades eletrocatalíticas com relação à redução de peróxido de hidrogênio e ácido tricloroacético. Os limites de detecção, a faixa linear de calibração e as sensibilidades dos eletrodos são, respectivamente, 0,01 μmol L, 0,02 a 0,20 μmol L e 98,80 μA μmol L para o peróxido de hidrogênio e 0,01 μmol L, 0,02 a 0.20 μmol L e 80,05 μA μmol L para o ácido tricloroacético.
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تاریخ انتشار 2010